Purple sweet potato-based cathode materials are constructed for Li-S batteries. Different activation approaches to the biomass carbon structures are investigated. The battery reveals a stable discharge capacity after the initial several cycles.
Lithium-sulfur (LiS) batteries are an upcoming battery technology that are reaching the first stages of commercial production in this decade. They are characterized by excellent gravimetric energy density, low-cost materials and low cycle lives, well suited to drone applications and to replace NMC batteries in electric vehicles.
The low cycle life of LiS batteries is caused by several different factors, including dendrite formation on the anode, the polysulfide shuttle effect and cathode swelling. Dendrite formation is one of the key challenges for any battery using lithium metal as an electrode.
By using lithium thioborophosphate iodide glass-phase solid electrolytes in all-solid-state lithium–sulfur batteries, fast solid–solid sulfur redox reaction is demonstrated, leading to cells with ultrafast charging capability, superior cycling stability and high capacity.
With promises for high specific energy, high safety and low cost, the all-solid-state lithium–sulfur battery (ASSLSB) is ideal for next-generation energy storage1–5. However, the poor rate performance and short cycle life caused by the sluggish solid–solid sulfur redox reaction (SSSRR) at the three-phase boundaries remain to be solved.
Sulfur cathodes are also prone to significant swelling (up to 80%) when Li 2 S is absorbed, placing significant stress on the electrode and leading to premature electrode failure. LiS batteries use specialized materials to mitigate these challenges.
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